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The benefit of this skill over Apply Poison is that you can use Poison Arrow in conjunction with other preparations such as Barbed Arrows.
Poison Tip Signet can also work with preparations and leave out an elite spot.
In combination with Barbed Arrows you can quickly spread -7 life degeneration over the whole enemy party due to the very low recharge time of Poison Arrow. Use a barbed weapon upgrade to enhance the bleeding duration for a long lasting degeneration at low cost.